SODIUM
SULFITE
|
PRODUCT
IDENTIFICATION
|
CAS
NO. |
7757-83-7
|
|
EINECS
NO. |
231-821-4 |
FORMULA |
Na2SO3 |
MOL
WT. |
126.04 |
H.S.
CODE
|
2832.10 |
TOXICITY |
Oral
mouse LD50: 820 mg/kg |
SYNONYMS |
Sodium
sulfite anhydrous; disodium sulfite; |
Natrii
Sulphis; Natrium Sulfurosum; Natriumsulfit (German);
sulfurous acid, disodium salt; exsiccated sodium sulfite;
Sodium sulfite (2:1); Sulfurous acid, sodium salt (1:2);
|
SMILES |
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
White
crystalline
powder
|
MELTING
POINT |
Decomposes
|
BOILING
POINT |
|
SPECIFIC
GRAVITY |
2.633 |
SOLUBILITY
IN WATER |
good |
pH |
9
|
VAPOR
DENSITY |
4.35 |
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health:
1 Flammability: 0 Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable
under ordinary conditions |
GENERAL
DESCRIPTION & APPLICATIONS
|
Sodium
Sulfite is a White
crystalline
or powder;
readily
soluble in water, decomposes
on heating. It is prepared from sulfur
dioxide and sodium carbonate or caustic soda. It
is a strong reducing agent and reacts with oxidants.
It is primarily used in pulp and paper industry.
It is used in water treatment as an oxygen scavenger
agent , in the photographic industry to protect
developer solutions from oxidation, in textile industry
as a bleaching, as a desulfurizing and as a dechlorinating
agent and in leather trade for the sulfitization
of tanning extracts. It is used in chemical manufacturing
as a sulfonation and sulfomethylation agent. It
is used in the production of sodium thiosulfate.
It is use in other applications include ore flotation,
oil recovery, food preservative, making dyes, and
detergent. It forms a bisulfite adduct with aldehyde and with ketones
to a sulfonic acid. It is used to purify or isolate aldehydes and ketones.
|
SALES
SPECIFICATION |
TECH
GRADE |
APPEARANCE
|
White
crystalline
powder
|
Na2SO3 |
96.0%
min |
SO2 |
48.8%
min |
IRON |
10ppm
max |
HEAVY
METALS |
10ppm
max |
pH |
9.5
- 10.5 |
FOOD
GRADE |
APPEARANCE
|
White
crystalline
powder
|
Na2SO3 |
98.0%
min |
SO2 |
50.0%
min
|
IRON |
5ppm
max |
ARSENIC |
0.5ppm
max |
HEAVY
METALS |
10ppm
max |
pH |
9.5
- 10.5 |
PHOTO
GRADE |
APPEARANCE
|
White
crystalline
powder
|
Na2SO3 |
97.5%
min |
SO2 |
49.5%
min
|
Na2S2O3 |
0.015%
max
|
IRON |
5ppm
max |
HEAVY
METALS |
10ppm
max |
pH |
9.5
- 10.5 |
TRANSPORTATION |
PACKING |
25kgs
, 1mt in Bag |
HAZARD
CLASS |
Not
regulated |
UN
NO. |
|
BISULFITE ADDUCTS WITH ALDEHYDE GROUPS |
Acetone
Sodium Bisulfite:
[CAS RN: 540-92-1, (CH3)2C(OH)SO3Na]
Crystals that have a slight sulfur dioxide odor and slightly fatty feel; freely
soluble in water, decomposed by acids; used in textile dyeing
and printing.
Sodium
Formaldehyde Bisulfite [CAS
RN: 870-72-4 CH3NaO4S] A compound used as a
fixing agent for fibers containing keratin, in metallurgy for flotation of
lead-zinc ores, and in photography
Indole-3-acetaldehyde
Sodium Bisulfite [CAS RN: 20095-27-6, C10H9NO · NaHSO3]
Glutaraldehyde bis(sodium bisulfite) [CAS
RN: 7420-89-5,
C5H12O8S2]
used
as an antiseptic
Menadione Sodium Bisulfite
[CAS RN: 57414-02-5, C11H9NaO5S]
a water-soluble derivative of menadione provitamin which
converted in the body to active vitamin K.
Glyoxal sodium bisulfite [CAS
RN: 332360-05-1, [CH(OH)SO3Na]2]
nonaqueous form of glyoxal |
OTHER
INFORMATION
|
Sulfate (also spelled sulphate in Europe) is any chemical compound containing
the SO42- ion related to sulfuric acid (H2SO4). Sulfates are salts or esters of
sulfuric acid, formed by replacing one or both of the hydrogens with a metal or a radical
as in sodium sulfate, Na2SO4.
Sulfates in which both hydrogens are
replaced are called normal sulfates. Bisulfate is a compound that has the HSO4- radical. Bisulfate (called also
hydrogen sulfate or acid sulfate) is a compound formed by replacing only one
hydrogen in sulfuric acid. Sulfite (also sulphite) is a compound that contain
the sulfite ion SO32-. Sulfites are salts or esters of sulfurous acid (H2SO3),
formed by replacing one or both of the hydrogens with a metal or a radical
as in sodium sulfite, Na2SO3.
Sulfites in which both hydrogens are
replaced are called normal sulfites. Bisulfite is a compound that has the HSO3- radical. Bisulfate (called also
hydrogen sulfite or acid sulfite) is a compound formed by replacing only one
hydrogen in sulfurous acid. The term of 'meta' or 'pyro' is the
chemical prefix for oxo acid formed through
the loss of one water molecule
(dehydration) from
two molecules of ortho acid by heating.
Pyrosulfuric acid is an example ( 2H2SO4 - H2O =
H2S2O7). Ortho acid is the
compound fully hydrated acid or its salts. Orthophosphoric acid is an example
(2·H3PO4 =
P2O5.3H2O), in contrast to the
less hydrated form, pyrophosphoric acid (2·HPO3 =
P2O5.H2O).
Na2O5S2
is called sodium metabisulfite
(2·HNaO3S
- H2O).
Sulfide is a compound
having one or more sulfur atoms in which the sulfur is connected directly to a
carbon, metal, or other nonoxygen atom; for example sodium sulfide, Na2S.
Sulfide ion is S2- with oxidation number -2. Bisulfide ion is an anion formed by
two sulfur atoms having an overall -2 charge, (S2)2-. Sulfamate is a salt of
sulfamic acid (HSO3NH2). Calcium sulfamate Ca(SO3NH2)2 is an example.
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